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Marine Geochemistry - Laboratory Methods



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in lab methods

Typical element to Calcium ratios in seawater, corals and forams

molar: 9.3 10-3 = e.g. 9.3 µM/mM or 9.3 mM/M
weight: 15 10-6 = e.g. 15 ng/mg or 15 µg/g..

 
 Seawater
Coral 
foram a

Seawater
Coral
foram

coral
foram
ratio
molar
molar
molar

weight
weight
weight

factor
factor
Mg/Ca
5.2
5 10-3
1-10 10-3

3.1
3 10-3
0.6-6 10-3

1 10-3
2 - 20 10-4
Sr/Ca
8-9 10-3
9.3 10-3
1-2 10-3

18-20 10-3
20 10-3
2.2-4.4 10-3

1
0.1 - 0.2
Ba/Ca
3-15 10-6
4-10 10-6
2-3 10-6

10-50 10-6
14-35 10-6
 5-10 10-6

1
1
U/Ca
1-1.6 10-6
1-2 10-6
5-15 10-9

6-10 10-6
6-12 10-6
 3-9 10-8

1
1 10-2
B/Ca

40 10-3

4-5 10-4
 

11 10-3
0.1-0.13 10-3
 

10-2
Mn/Ca
1.8-3 10-8
 
1-20 10-5

24-40 10-9
 
 1.4-28 10-5


103 - 104
Cd/Ca
10-10-10-7
 
5-25 10-8

0.3-300 10-9
 
1.4-7 10-7


1 - 103
Li/Cab
2.4 10-3
4-18 10-6 
2-6 10-6

4.2 10-4
0.7-3 10-6 
0.3-1 10-6

10-3 10-3
Li/Mgb
4.7 10-4
2-5 10-3 
0.5-1.5 10-3

1.4 10-4
0.6-1.5 10-3 
0.15-0.5 10-3

10 1 - 3

 

 

 







 




a data from Harding, D. J., J. W. Arden, and R. E. M. Rickaby (2006), A method for precise analysis of trace element/calcium ratios in carbonate samples using quadrupole inductively coupled plasma mass spectrometry, Geochem. Geophys. Geosyst., 7, Q06003, doi:10.1029/2005GC001093.

b data from Marchitto, T.M., Bryan, S.P., Doss, W., McCulloch, and P. Montagna (2018) A simple biomineralization model to explain Li, Mg, and Sr incorporation into aragonitic foraminifera and corals, EPSL 481, 20-29. https://doi.org/10.1016/j.epsl.2017.10.022.

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