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Specific Surface Determination : QUANTACHROME Quantasorb
BET instrument Dewar liquid N Dewar liquid N sample cell sample preparation beaker
type QUANTACHROME Quantasorb
short description of method Detection of specific grain surface by nitrogen adsorption at liquid nitrogen temperature in a flow-through cell. Heat conductivity detector detects heat conductivity change in He/N gas mixture after nitrogen adsorption to sample surfaces at liquid nitrogen temp followed by desorption at room temperature.
sample cells Flow-through cells, quartz glass, access tube diameter 2 mm, cell volumes 2.5 cm³ / 10 cm³
Gas supply 10L cylinder with Gas mixture 30% N in 70 % He
Nitrogen 4.6 for sample preparation and calibration
sample preparation

heating under Nitrogen flow min. 1 h at 60°C (depends on sample)

sample size

Physically to fit into the sample cell: grains < 2mm,
The small cell has a volume of 2 cm3, the large one in picture above has 10 cm3. Assuming a powder sample takes about 50% of the volume:
max. about 2.5 grams (of sediment, density 2.7g/m3) in normal cell / max. 12.5 grams in large cell.
cube-shaped grains without any porosity or surface structure should be less than 25µm of sediment if you use the normal cell and less than 125µm when you use the big cell. Realistically grain size might be about a factor 2 larger (thus 50 / 250 µm) due to irregular shapes, surface structure and/or porosity.
see quick specific area estimate below: small cell: 2.5 *6 / (2.7*25) or large cell: 12.5 * 6 / (2.7 * 125) = 0.22 m2 absolute surface area in cell

calibration

simulation of desorption peak by injection of appropiate amount of nitrogen into N/He gas stream

detection limit

0.2 m² absolute surface ( i.e. 5 grams of sediment material with a specific surface of 0.04 m²/g or
0.1 gram of a material with a specific surface of 2 m²/g)

 analysis time

1 sample

10 similar samples

6 hours

2 days
 quick estimate

simple grain size to specific surface conversion for cube-shaped particles
A = m * 6/(d*rho)
A - specific surface in m²/g
m - sample mass in g

d - grain size in µm
rho - density in g/cm3

Amount of powder that fits into cell assuming powder occupies half the volume
m = 0.5 * V * rho
V - sample cell volume in cm3:  2 cm3 for small cell, 10
cm3 for large cell

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page updated on

 07Mar23,.

page created by M.Kölling & T.Feseker